That is, chuck in a load of cold water into the bucket (a couple of litres, then slosh it all about, strain it into another bucket; put the rinsed rhubarb back into bucket 1, splosh in some more water, whizz it about then drain off into the second bucket.
Repeat until you have rinsed rhubarb in bucket 1; and just under about 4l in bucket 2. It is bucket 2 which you then add a can or grape concentrate (wilko half price at the mo) or a carton of white grape juice would do; then a tsp of pectolase, a piece of lemon rind, a tsp of yeast nutrient and a tsp of yeast.
Stir, cover, and stand well back. The pieces of rhubarb in bucket one will still be hardish, and you can pop 'em in your mouth like sweeties.

In your case, if I really did think it was just a bit of mould, I'd scoop it off with a spoon and make the first rinse with boiling water to kill any nasties.
You might want to wait for further opinion on this, mind - the others will be along soon, no doubt. In the meantime, can you take a pic of the bucket and post it here?

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